Editorial Feature

What are the Characteristics and Properties of Quartz?

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Quartz is a silicate mineral—composed of silicon and oxygen—that is in abundance within the Earth’s crust. It can be found naturally as lumps of the just the mineral itself, or it can be present in a number of rocks—with the most common and well-known example being in granite (alongside feldspar and mica). While it is one of the most well-known minerals, this article is dedicated to looking at the different characteristics and properties which quartz has.

Quartz can be found in almost every mineral environment and can also be found within all three rock classes (sedimentary, igneous, and metamorphic). Chemically, quartz is only composed of silicon and oxygen atoms and has a chemical formula of SiO2. At the atomic level, the silicon and oxygen atoms are arranged in a continuous framework of tetrahedra, where four oxygen atoms surround a single silicon atom, but the oxygen atoms are located between two tetrahedra (i.e. the oxygen are utilized in two tetrahedra, hence the molecular formula). The tetrahedron arranges themselves into a 3D network by forming helical structures. These helical structures take two common forms, which are threefold and sixfold helices, and six helices (regardless of the type) join together to form ‘channels’ through the mineral.

There are two different structural forms of quartz, which are known as α-quartz and β-quartz. While both forms are chiral (even though the individual tetrahedrons are achiral), α-quartz adopts a trigonal crystal structure, whereas β-quartz adopts a hexagonal crystal structure. Β-quartz is known as the high-temperature form of quartz, and the atomic structure rearranges easily—via a rotation of the tetrahedra—once α-quartz is heated up to 573 °C. Quartz can also form left-handed and right-handed crystals, depending on which way the helices turn during formation, and the morphology and crystal structures of each handed form are mirror opposites of the other form.

There are many different aspects and properties to a mineral, from the color to its hardness, to how its layers cleave under stress and more. Quartz can be in many different colors. In its purest form, it is a clear or white color, but different impurities within the atomic lattice can cause the color to change to purple, pink, brown, black, gray, green, orange, yellow, blue, or red. In some cases, the color can be banded or multiple colors depending on the impurity levels. For example, one common form of quartz that has impurities is amethyst, where the presence of iron or other transition metal ions causes the color to turn purple/lilac. Therefore, depending on whether a specimen is pure or not, it’s transparency can range from transparent to opaque.

Quartz also has a vitreous luster, which means that it interacts with light in the same way that glass does. In terms of whether you can see visible crystals, it depends on how transparent the quartz sample is. Transparent quartz samples tend to be macrocrystalline and the different crystals can be seen with the human eye. However, translucent and opaque samples are cryptocrystalline, and the crystals are only just about visible with a microscope, never mind the human eye. Quartz also has a white streak (i.e. the color of the mineral when it is in a powdered form).

In terms of hardness, quartz is relatively hard for a mineral and has a Moh’s scale hardness of 7 (out 10 – with diamond being a 10). Quartz is also very stable to high temperatures and harsh chemicals, with it requiring very strong acids, such as hydrofluoric acid, to dissolve it. Many other minerals will dissolve in weaker acids. However, quartz is very brittle, but because it does not exhibit cleavage, it is relatively strong to mechanical stress. It is, however, susceptible to conchoidal (rounded and shell-like) fractures and some of the crystal faces can exhibit striations—which are a series of parallel marks/grooves in the crystal face.

Quartz also exhibits a number of other properties. Quartz has a specific gravity between 2.6 and 2.7 depending on the type of quartz, and it can polarize any light which passes through it (how it polarizes the light depends on the handedness of the helices), with a birefringence of up to 0.009. Quartz is also piezoelectric, so it can generate an electrical current under applied stress, as well as being triboluminescent (the generation of light when it is crushed or damaged), and some forms can also exhibit fluorescence.

Sources and Further Reading

 

 

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Liam Critchley

Written by

Liam Critchley

Liam Critchley is a writer and journalist who specializes in Chemistry and Nanotechnology, with a MChem in Chemistry and Nanotechnology and M.Sc. Research in Chemical Engineering.

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Comments

  1. John Matacola John Matacola United States says:

    the piezo effect of quartz makes me wonder....how much energy would be needed to utilize an irradiated quartz crystal in the process of producing power, storing power(in the compacted resulting structure), or producing light which could be converted into energy? Perhaps even powering 'solar cells' when there is no sunlight.

The opinions expressed here are the views of the writer and do not necessarily reflect the views and opinions of AZoMining.com.

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