Editorial Feature

Azoproite - Occurrence, Properties, and Distribution

Azoproite is an orthorhombic-dipyramidal black mineral containing titanium, oxygen, magnesium, iron and boron. It was first observed in Tazheran alkalic massif, west of Lake Baikal, eastern Siberia, Russia in 1970. The mineral was named after a Russian acronym honoring the Study of Deep Zones of the Earth’s Crust.

Properties of Azoproite

The following are the key properties of Azoproite:

  • Cell Data
    • Space Group: Pbam
    • a = 9.26(1)
    • b = 12.25(1)
    • c = 3.01(1)
    • Z = 4.
  • Crystal Data
    • Orthorhombic
    • Point Group: 2/m 2/m 2/m
    • As prismatic crystals, often striated and skeletal, to 2 cm, typically poorly terminated, with a diamond-shaped outline on {001}
    • X-ray Powder Pattern: 2.52 (10d), 5.07 (8), 2.16 (6), 2.02 (6), 2.77 (5b), 2.11 (5), 1.900 (5).
  • Chemical Composition
    Elements Content
    TiO2 15.4
    B2O3 19.07
    Fe2O3 16.01
    FeO 5.16
    MnO 0.11
    MgO 45.01
    Na2O Trace
    Total 100.76
  • Optical Properties
    • Optical Class: Biaxial (+)
    • Pleochroism: Strong
    • X = pale bluish green
    • Y = dark green;
    • Z = brownish red
    • Absorption: Z > Y > X
    • α = 1.799(2)
    • β = 1.822(3)
    • γ = 1.855(5)
    • 2V (meas.) = > 70°
    • 2V (calc.) = 80°.
  • Estimated Properties
    Electron density Bulk density (electron density) = 3.54 g/cm3
    note: Specific gravity of Azoproite = 3.63 g/cm3
    Photoelectric PEAzoproite = 6.65 barns/electron
    U = PEAzoproite x ρ Electron density = 23.52 barns/cm3
    Fermion index Fermion index = 0.05
    Boson index = 0.95

    Radioactivity

    Azoproite is not radioactive.

How to Identify Azoproite

Azoproite is a black-colored mineral having a gray streak, adamantine luster, distinct cleavage and transparent to sub-opaque appearance. It exhibits very brittle fractures producing small, conchoidal fragments. The density of the mineral is 3.63 g/cm3, and its hardness is 5.5.

Global Distribution

Azoproite is widely distributed in the Tazheran alkalic massif, west of Lake Baikal, eastern Siberia, Russia.

Occurrence of Azoproite and Useful Mineral Association

Azoproite occurs as an uncommon late-stage mineral in the border zone in magnesian contact-metamorphic rocks associated with syenites. This mineral is closely associated with forsterite, geikielite, perovskite, tazheranite, baddeleyite, clinohumite, brucite, ludwigite and calcite.

References

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