Editorial Feature

Carbocernaite – Occurrence, Properties, and Distribution

Carbocernaite was named after the key chemical components -CARBOnate, CERium, and NAtrium (sodium).

Properties of Carbocernaite

The following are the key properties of carbocernaite:

  • Cell Data
    • Space group: Pb2m
    • a = 6.430
    • b = 7.301
    • c = 5.214
    • Z = 2
  • Crystal Data
    • Orthorhombic
    • Point group: mm2
    • As tabular crystals with wedge-like terminations, to 4 mm, with dominant {100}, minor {010}, {001}, {021}, {540}, {210}, vicinal {305} and {210}
    • as grains and exsolution lamellae
    • X-ray powder pattern: 3.00 (10), 2.015 (9), 1.813 (8), 2.60 (7b), 2.29 (7b), 3.66 (5), 2.082 (5)
  • Chemical Composition
    Elements Content 1 Content 2
    CO2 33.85 [32.02]
    SrO 17.77 18.74
    CaO 16.68 17.15
    La2O3 8.78 13.26
    Ce2O3 10.27 10.16
    BaO 5.24 1.64
    Na2O 3.15 3.83
    Nd2O3 2.47 1.82
    H2O 1.22 -
    Pr6O11 0.99 0.76
    MnO - 0.69
    FeO 0.53 -
    Gd2O3 0.39 -
    Sm2O3 0.30 0.31
    Total 101.64 [100.38]
  • Optical Properties
    • Optical Class: Biaxial (–)
    • Orientation: X = b; Y = a; z = c
    • Dispersion: r > v, marked
    • α = 1.569(2); β = 1.679(2); γ = 1.708(2)
    • 2V(meas.) = n.d.
    • 2V(calc.) = 52?
  • Estimated Properties
    Electron density Bulk density (electron density) = 3.39 g/cm3
    note: Specific gravity of carbocernaite = 3.62 g/cm3
    Photoelectric PECarbocernaite = 124.93 barns/electron
    U=PECarbocernaite x ρ electron density = 423.03 barns/cm3
    Fermion index Fermion index = 0.02
    Boson index = 0.98
    Radioactivity Carbocernaite is radioactive

How to Identify Carbocernaite

Carbocernaite can be identified in the field by its color variations such as brown, yellow, yellow brown and white. It is sometimes colorless. Its transparent to translucent form has {100} indistinct, {021} indistinct, {010} indistinct cleavage.

This mineral has a vitreous - greasy luster with white streak. The fracture on this mineral is brittle. The density of carbocernaite is 3.53 g/cm3 with a hardness of 3 – approximate to calcite.

Global Distribution

Carbocernaite is distributed in the following places:

  • Russia - From the Vuoriyarvi carbonatite complex and in the Khibiny massif, Kola Peninsula; at the Ozernyi carbonatite, southeastern Sakha
  • Afghanistan - At the Khanneshin carbonatite complex
  • China - In the Bayan Obo Fe–Nb–RE deposit, 130 km north of Baotou, Inner
  • Mongolia, and at Weishan, Shandong Province
  • Vietnam -From the Phan Si Pan Range
  • India - At the Sarnu-Dandali alkaline complex, Barmer District, Rajasthan,
  • Canada - Ontario, Mont Saint-Hilaire, Quebec.

Occurrence of Carbocernaite and Useful Mineral Association

Carbocernaite typically occurs in an uncommon accessory mineral in dolomite–calcite carbonatite associated with an alkaline ultramafic massif; exsolved from calcite and in a carbonatite dike in fenitized melanephelinite.

It is often associated with minerals such as chlorite, ankerite, alstonite, anatase, quartz, dolomite, barite, mckelveyite-(Y), calkinsite-(Ce) and khanneshite.

References

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