Editorial Feature

Macdonaldite - Occurrence, Properties, and Distribution

Macdonalite is a rare barium silicate mineral, which was first discovered in 1965 from Big Creek - Rush Creek sanbornite deposit, Fresno Co. California.

It was named for Gordon Andrew Macdonald, an American volcanologist at the University of Hawaii.

Properties of Macdonaldite

The following are the key properties of Macdonaldite:

  • Cell Data
    • Space Group: Bmmb; B2mb; or Bm21b
    • a = 14.06(1)
    • b = 23.52(2)
    • c = 13.08(1)
    • Z = 4

  • Crystal Data
    • Orthorhombic
    • Point Group: 2/m 2/m 2/m or mm2
    • Needle-like crystals show {010}, {001}, and {100}, and are elongated along [100], to 6mm; also fibrous, in radiating aggregates, and granular
    • X-ray Powder Pattern: 6.5 (100), 4.36 (80), 6.3 (50), 3.36 (50), 3.02 (45), 2.74 (45), 8.9 (40)

  • Chemical Composition
    Elements Content
    SiO2 61.1
    CaO 14.8
    LOI 13.7
    BaO 10.2
    MgO <6.05
    Al2O3 0.06
    SrO <0.05
    TiO2 0.01
    FeO <0.01
    MnO 0.004
    Total [100.00]

  • Optical Properties
    • Optical Class: Biaxial (+) or (-)
    • Orientation: X = c; Y = b; Z = a
    • α = 1.518(2)
    • β = 1.524(2)
    • γ = 1.530(2)
    • 2V(meas.) = 90(5)°
    • 2V(calc.) = 90°

  • Estimated Properties
    Electron density Bulk density (electron density) = 2.35 g/cm3
    note: Specific gravity of Macdonaldite = 2.36 g/cm3
    Photoelectric PEMacdonaldite = 38.38 barns/electron
    U = PEMacdonaldite x ρElectron density = 90.28 barns/cm3
    Fermion index Fermion index = 0.02
    Boson index = 0.98
    Radioactivity
    Macdonaldite is not radioactive

How to Identify Macdonaldite

Macdonaldite is a transparent, colorless or white mineral, having perfect cleavage, vitreous luster, and white streak. It forms needle-like crystals.

The hardness of macdonaldite ranges from 3.5 to 4, and its density is 2.27 g/cm3.

Global Distribution

Macdonaldite is widely distributed in the following places:

  • Big Creek-Rush Creek area, Fresno Co.
  • Trumbull Peak, near Incline, Mariposa Co. California, USA

Occurrence of Macdonaldite and Useful Mineral Association

Macdonaldite is disseminated in a sanbornite-quartz-bearing metamorphic rock, and occurs as fracture coatings and veinlets.

It is closely associated with quartz and sanbornite.

References

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